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Energy efficiency in industrial systems remains a major challenge, as conventional data-driven models are often constrained by limited precision and insufficient data. Integrating the physical laws that govern energy systems can enhance performance and ensure greater physical plausibility; however, such models often struggle with loss computation and often overlook dynamic interactions among subsystems, leading to excessive simplification and reduced real-world utility. Accordingly, this study explores a theoretical framework for constructing a conservation-law-guided neural network to improve energy-efficiency forecasting in industrial processes. The framework embeds physical principles directly into floating nodes built upon a long short-term memory (LSTM) architecture, enabling the model to capture relationships among process variables more effectively. At the same time, gradient aggregation enhances both fluidity and interpretability. Performance was assessed through two large-scale industrial case studies—vinyl chloride monomer production and detergent powder manufacturing—where the proposed model achieved notable gains in prediction accuracy and overall reliability, delivering test prediction improvements of 12.2% and 5.87% compared to previously published approaches. Compared with methods that rely on network architecture modifications, the proposed model demonstrated superior reliability and reproducibility in energy-efficiency forecasts. Furthermore, the model effectively identified energy inefficiencies, resulting in a 4.21% decrease in energy use and a corresponding reduction of 377.35 tons in carbon emissions.